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canonical meaning in chemistry

Meaning of canonical form. This term is borrowed from mathematics, where it is used to refer to concepts that are unique and/or natural. We can imagine a collection of boxes with equal volumes, and equal number of particles. Canonical definition is - of, relating to, or forming a canon. Return to top of page. ÈH2 Í≠ÈHÍ2 = È(ÈHÍ≠H)2 ÍπH2. We can also show that in the canonical ensemble the mean square fluc-tuation of energy is much smaller than average energy squared, i.e. Also known as canonicity or canonicality. How to use canonical in a sentence. What does canonical form mean? (noun) ... (chemistry) Any of a set of ... be remarked that the counting of constants is not a sure guide to the existence of a conjectured canonical form. Mathematical definition; Canonical ensemble refers to a statistical ensemble which is specified by system volume (V) ,number of particles (N) and temperature (T). $\endgroup$ – Alex Youcis Sep 11 '13 at 8:10 Canonical Form – In Boolean algebra,Boolean function can be expressed as Canonical Disjunctive Normal Form known as minterm and some are expressed as Canonical Conjunctive Normal Form known as maxterm . Canonical, in computer science, is the standard state or behavior of an attribute. Triangular canonical form: Let be a linear operator. Definition of canonical form in the Definitions.net dictionary. canonical ensemble and canonical ensemble are equivalent. $\begingroup$ @user61001 The actual definition of canonical is a little sophisticated, and it doesn't really apply in this case (although it probably applies in other cases you're thinking of). The entire collection is … See more. Information and translations of canonical form in the most comprehensive dictionary definitions resource on the web. NOTE: In the below, I'm implicitly discussing a ground-state, closed-shell wavefunction, where all occupied orbitals are doubly occupied.The discussion would be similar for open-shell wavefunctions, but there are complexities that I won't address here. (mathematics) A standard or normal presentation of a mathematical entity. Canonical Structures and Resonance Lewis / Kekulé structures A through D are constitutional isomers having the molecular formula CN 2 H 2.The remaining structures include canonical formulas which should be incorporated in a resonance description of these four compounds. The triangular form, Jordan canonical form and row echelon form are some major canonical forms in Linear Algebra. Canonical definition, pertaining to, established by, or conforming to a canon or canons. Search the Dictionary for More Terms. What does canonical-form mean? Canonical ensemble refers to the statistical ensemble that represents possible states of mechanical system in thermal equilibrium having thermal energy reservoir at fixed temperature. In Minterm, we look for the functions where the output results in “1” while in Maxterm we look for function where the output results in “0”. The Canonical Ensemble Last updated; Save as PDF Page ID 78459; The Boltzmann Distribution; The most practical ensemble is the canonical ensemble with N, V, and T fixed. The word is just misused, in some sense, to mean "natural", "obvious", or "dictated by circumstances". The standard representation of canonical form is used in many fields like Linear algebra, graph theory, Operations Research, Computer science, and so on. Presentation of a mathematical entity pertaining to, or conforming to a canon form, Jordan form... Fixed temperature mathematical entity, in computer science, is the standard state or behavior of an attribute and number. 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